Tuning Acid-Metal Synergy in m-Cresol Hydrodeoxygenation over Bifunctional Pt/Aluminosilicate Catalysts

James A. Hunns; Lee J. Durndell; Xingguang Zhang; Muxina Konarova; Adam F. Lee; Karen Wilson

doi:10.1021/acscatal.4c00402

Tuning Acid-Metal Synergy in m-Cresol Hydrodeoxygenation over Bifunctional Pt/Aluminosilicate Catalysts

James A. Hunns
, Lee J. Durndell
, Xingguang Zhang
, Muxina Konarova
, Adam F. Lee^*
, Karen Wilson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Strong synergy between proximate Bro̷nsted acid and metal sites over a Pt/amorphous silica-alumina (ASA) catalyst confers striking activity and selectivity enhancements for m-cresol hydrodeoxygenation to methylcyclohexane, a fuel additive and potential liquid organic hydrogen carrier for storing renewable energy.

Original language	English
Pages (from-to)	7052-7061
Number of pages	10
Journal	ACS Catalysis
Volume	14
Issue number	9
Early online date	22 Apr 2024
DOIs	https://doi.org/10.1021/acscatal.4c00402
Publication status	Published - 3 May 2024

ASJC Scopus subject areas

Catalysis
General Chemistry

Keywords

bifunctional
biofuel
biomass
catalysis
hydrodeoxygenation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/acscatal.4c00402

Cite this

@article{82fd51066f5b408887893ba097b9d120,

title = "Tuning Acid-Metal Synergy in m-Cresol Hydrodeoxygenation over Bifunctional Pt/Aluminosilicate Catalysts",

abstract = "Strong synergy between proximate Bro̷nsted acid and metal sites over a Pt/amorphous silica-alumina (ASA) catalyst confers striking activity and selectivity enhancements for m-cresol hydrodeoxygenation to methylcyclohexane, a fuel additive and potential liquid organic hydrogen carrier for storing renewable energy.",

keywords = "bifunctional, biofuel, biomass, catalysis, hydrodeoxygenation",

author = "Hunns, \{James A.\} and Durndell, \{Lee J.\} and Xingguang Zhang and Muxina Konarova and Lee, \{Adam F.\} and Karen Wilson",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = may,

day = "3",

doi = "10.1021/acscatal.4c00402",

language = "English",

volume = "14",

pages = "7052--7061",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Tuning Acid-Metal Synergy in m-Cresol Hydrodeoxygenation over Bifunctional Pt/Aluminosilicate Catalysts

AU - Hunns, James A.

AU - Durndell, Lee J.

AU - Zhang, Xingguang

AU - Konarova, Muxina

AU - Lee, Adam F.

AU - Wilson, Karen

PY - 2024/5/3

Y1 - 2024/5/3

N2 - Strong synergy between proximate Bro̷nsted acid and metal sites over a Pt/amorphous silica-alumina (ASA) catalyst confers striking activity and selectivity enhancements for m-cresol hydrodeoxygenation to methylcyclohexane, a fuel additive and potential liquid organic hydrogen carrier for storing renewable energy.

AB - Strong synergy between proximate Bro̷nsted acid and metal sites over a Pt/amorphous silica-alumina (ASA) catalyst confers striking activity and selectivity enhancements for m-cresol hydrodeoxygenation to methylcyclohexane, a fuel additive and potential liquid organic hydrogen carrier for storing renewable energy.

KW - bifunctional

KW - biofuel

KW - biomass

KW - catalysis

KW - hydrodeoxygenation

UR - https://www.scopus.com/pages/publications/85191197735

U2 - 10.1021/acscatal.4c00402

DO - 10.1021/acscatal.4c00402

M3 - Article

AN - SCOPUS:85191197735

SN - 2155-5435

VL - 14

SP - 7052

EP - 7061

JO - ACS Catalysis

JF - ACS Catalysis

IS - 9

ER -

Tuning Acid-Metal Synergy in m-Cresol Hydrodeoxygenation over Bifunctional Pt/Aluminosilicate Catalysts

Abstract

ASJC Scopus subject areas

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this