TY - JOUR
T1 - The use of porous high surface area calcium carbonate for the adsorption of dissolved and colloidal substances from thermo mechanical pulp filtrates
AU - Gantenbein, D
AU - Schoelkopf, J
AU - Matthews, GP
AU - Gane, PAC
PY - 2012/1/1
Y1 - 2012/1/1
N2 - Talc is often used to control unwanted deposition of resins when the colloidal concentration is high, but when the colloidal concentration is low, adsorbs substantial amounts of dissolved carbohydrates. Natural calcium carbonate and surface hydrophobised calcium carbonate largely avoid this problem, adsorbing limited amounts of solid species at neutral to alkaline pH. Modified calcium carbonate (mcc), displaying an internally porous structure, high specific surface area and both anionic and cationic surface sites, has even greater specificity for particulate pitch adsorption. The mixed charges on the surface of mcc also give rise to selective adsorption of soluble species at high doses, at adsorption sites inaccessible to pitch.
AB - Talc is often used to control unwanted deposition of resins when the colloidal concentration is high, but when the colloidal concentration is low, adsorbs substantial amounts of dissolved carbohydrates. Natural calcium carbonate and surface hydrophobised calcium carbonate largely avoid this problem, adsorbing limited amounts of solid species at neutral to alkaline pH. Modified calcium carbonate (mcc), displaying an internally porous structure, high specific surface area and both anionic and cationic surface sites, has even greater specificity for particulate pitch adsorption. The mixed charges on the surface of mcc also give rise to selective adsorption of soluble species at high doses, at adsorption sites inaccessible to pitch.
U2 - 10.3183/npprj-2012-27-03-p631-638
DO - 10.3183/npprj-2012-27-03-p631-638
M3 - Article
SN - 0283-2631
VL - 27
SP - 631
EP - 638
JO - Nordic Pulp and Paper Research Journal
JF - Nordic Pulp and Paper Research Journal
IS - 3
ER -