Mass spectrometry of polycyclic tetracarboxylic ('ARN') acids and tetramethyl esters.

Paul A. Sutton, Benjamin E. Smith, Steven J. Rowland*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Polycyclic C(80) tetracarboxylic (so-called 'ARN') acids are found as calcium salts in deposits which form in certain oilfield pipelines and equipment. Characterisation of these acids is important for improving the prediction and hence avoidance or minimisation of oilfield deposition problems. Although several of the acids have been isolated and characterised (as regioisomeric mixtures) by nuclear magnetic resonance spectroscopy, mass spectrometric methods are likely to be much more useful for the routine analysis of oils and deposits containing the acids. A publication summarising the mass spectra of the purified acids and major derivatives might thus be a very useful source of reference for scientists and technologists studying these unusual compounds. We now report the characterisation of several of the purified acids and of the tetramethyl esters by electrospray ionisation mass spectrometry (ESI-MS) in both positive ion and negative ion modes, by multistage ESI-MS with a suggested rationalisation of the ions produced, by positive ion atmospheric solids analysis probe (ASAP) atmospheric pressure chemical ionisation (APCI), and by positive ion electron ionisation (EI)-MS. Tentative identifications of C(80) acyclic, mono-, bi- and tricylic tetraacids and the δ(13)C isotope values of a mixture of the semi-pure acids determined by MS are also reported for the first time.
Original languageEnglish
Pages (from-to)3195-3204
Number of pages0
JournalRapid Commun Mass Spectrom
Volume24
Issue number21
DOIs
Publication statusPublished - 15 Nov 2010

Keywords

  • Carboxylic Acids
  • Chromatography
  • High Pressure Liquid
  • Esters
  • North Sea
  • Petroleum
  • Polycyclic Compounds
  • Spectrometry
  • Mass
  • Electrospray Ionization

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