Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.

Aleksandra Ziarko; Thomas J.A. Slater; Mark A. Isaacs; Lee J. Durndell; Christopher M.A. Parlett

doi:10.1039/d3cy00198a

Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.

Aleksandra Ziarko
, Thomas J.A. Slater
, Mark A. Isaacs
, Lee J. Durndell
, Christopher M.A. Parlett^*

^*Corresponding author for this work

School of Geography, Earth and Environmental Sciences

Aston University
Cardiff University
RAL
University College London
Rutherford Appleton Laboratory
University of Manchester

Research output: Contribution to journal › Article › peer-review

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Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

Original language	English
Number of pages	0
Journal	Catalysis Science & Technology
Volume	0
Issue number	0
Early online date	12 May 2023
DOIs	https://doi.org/10.1039/d3cy00198a
Publication status	E-pub ahead of print - 12 May 2023

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title = "Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.",

abstract = "Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.",

author = "Aleksandra Ziarko and Slater, \{Thomas J.A.\} and Isaacs, \{Mark A.\} and Durndell, \{Lee J.\} and Parlett, \{Christopher M.A.\}",

year = "2023",

month = may,

day = "12",

doi = "10.1039/d3cy00198a",

language = "English",

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journal = "Catalysis Science \& Technology",

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T1 - Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.

AU - Ziarko, Aleksandra

AU - Slater, Thomas J.A.

AU - Isaacs, Mark A.

AU - Durndell, Lee J.

AU - Parlett, Christopher M.A.

PY - 2023/5/12

Y1 - 2023/5/12

N2 - Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

AB - Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

UR - https://pearl.plymouth.ac.uk/gees-research/531/

U2 - 10.1039/d3cy00198a

DO - 10.1039/d3cy00198a

M3 - Article

SN - 2044-4753

VL - 0

JO - Catalysis Science & Technology

JF - Catalysis Science & Technology

IS - 0

ER -

Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation.

Abstract

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